ARALDITE® AW 4804 / HARDENER HW 4804

ARALDITE® AW 4804 / HARDENER HW 4804 is an aluminium-filled epoxy adhesive providing outstanding temperature resistance. The system offers a long open time and good chemical resistance.

RTU Product Type: Structural Adhesive

Chemical Family: Epoxy & Epoxy Derivatives

Features: Chemical Resistant, Good Environmental Resistance, Long Open Time, Long Potlife, Self-Leveling, Very Good Heat Resistance

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Enhanced TDS

Identification & Functionality

Features & Benefits

Ready-to-Use Product Features
Product Properties
  • Excellent heat resistance up to 210 °C after post-cure
  • Self levelling
  • Good environmental resistance
  • Long pot life

Applications & Uses

Applications
  • The resin/hardener mix may be applied manually or robotically to the pretreated and dry joint surfaces. 
  • Huntsman stresses that proper adhesive joint design is critical for a durable bond.
  • The joint components should be assembled and secured in a fixed position as soon as the adhesive has been applied.

Regulatory & Compliance

Certifications & Compliance

Technical Details & Test Data

Cured Properties

Typical Cured Properties

  • Unless otherwise stated, the figures given below were all determined by testing standard specimens made by lap-jointing 114 x 25 x 1.6 mm strips of aluminium alloy. The joint area was 12.5 x 25 mm in each case.
  • The figures were determined with typical production batches using standard testing methods. They are provided solely as technical information and do not constitute a product specification.

Average lap shear strengths of typical metal-to-metal joints (ISO 4587) (typical average values)

  • Cured 2h/120°C
  • Pretreatment - Sand blasting + degreasing

ARALDITE® AW 4752 / HARDENER HW 4753 - Cured Properties - 1

Lap shear strength versus temperature (ISO 4587) (typical average values)

  • Cured for 2h/120 °C
  • Pretreatment - Sand blasting + degreasing

ARALDITE® AW 4752 / HARDENER HW 4753 - Cured Properties - 1

Lap shear strength versus immersion in various media (ISO 4587) (typical average values)

  • Unless otherwise stated, L.S.S. was determined after immersion for 90 days at 23°C
  • Cure 2 hours at 120°C
  • Pretreatment - Sand blasting + degreasing

ARALDITE® AW 4752 / HARDENER HW 4753 - Cured Properties - 1

Lap shear strength versus heat ageing (ISO 4587) (typical average values)

  • Cure: 16 hours at 40°C
  • Pretreatment - Sand blasting + degreasing

ARALDITE® AW 4752 / HARDENER HW 4753 - Cured Properties - 1

Typical Mechanical Properties

Property Value Unit Test Method at Condition
Tensile Strength 53 MPa ISO 527

Cure: 24 hours at RT + 2 hours at 90°C, tested at 23°C

Tensile Modulus 6200 MPa ISO 527

Cure: 24 hours at RT + 2 hours at 90°C, tested at 23°C

Elongation at Break 1.4 % ISO 527

Cure: 24 hours at RT + 2 hours at 90°C, tested at 23°C

Shore D Hardness 90 Shore D ISO 868

Cure: heated up gradually up to 180°C

Coefficient of Thermal Expansion 50 × 10⁻⁶ K⁻¹ ISO 11359

Cure: heated up gradually up to 180°C

Glass Transition Temperature (Tg) by DSC

Cure Cycle Tg (onset) Tg (midpoint) Unit
1h at 80°C 55°C 60°C °C
1h at 120°C 110°C 130°C °C
2h at 120°C 120°C 140°C °C
1h at 150°C 150°C 160°C °C
1h at 120°C + 1h at 180°C 155°C 170°C °C

 

Processing Information

Pretreatment

  • The strength and durability of a bonded joint are dependent on proper treatment of the surfaces to be bonded.
  • At the very least, joint surfaces should be cleaned with a good degreasing agent such as acetone or other proprie- tary degreasing agents in order to remove all traces of oil, grease and dirt. Low-grade alcohol, gasoline (petrol) or paint thinners should never be used.
  • The strongest and most durable joints are obtained by either mechanically abrading or chemically etching (“pick- ling”) the degreased surfaces.
  • Abrading should be followed by a second degreasing treatment.
Mix Ratio Parts by Weight

Parts by Volume

Araldite® AW 4804 100 100
Hardener HW 4804 15 28

Equipment maintenance

  • All tools should be cleaned with hot water and soap before adhesives residues have had time to cure.
  • The removal of cured residues is a difficult and time-consuming operation.
  • If solvents such as acetone are used for cleaning, operatives should take the appropriate precautions and, in addition, avoid skin and eye contact.

Typical cure requirements

  • To achieve optimum performance properties an elevated temperature cure is recommended. This adhesive will not reach sufficient cure at temperatures below 100°C.
  • Suggested cure schedules are:
  • 2h at 120°C
  • 1h at 150°C
  • 1h at 120°C + 1h at 180°C

Storage & Handling

Storage and Handling Precautions

       Storage

  • Araldite® AW 4804 and Hardener HW 4804 must be stored at 2-18°C in the original sealed containers.

       Handling Precautions

  • Our products are generally quite harmless to handle provided that certain precautions normally taken when handling chemicals are observed.
  • The uncured materials must not, for instance, be allowed to come into contact with food- stuffs or food utensils, and measures should be taken to prevent the uncured materials from coming in contact with the skin, since people with particularly sensitive skin may be affected.
  • The wearing of impervious rubber or plastic gloves will normally be necessary; likewise the use of eye protection.
  • The skin should be thoroughly cleansed at the end of each working period by washing with soap and warm water.
  • The use of solvents is to be avoided. Disposa- ble paper - not cloth towels - should be used to dry the skin.
  • Adequate ventilation of the working area is recommended.

Other

Appearance
Grey paste
Physical Properties
ValueUnitsTest Method / Conditions
Specific Gravityapprox. 1.65-
Viscosityapprox. 17.0 Pa.sPa.s