EPOXY CURING AGENT ECA 29

EPOXY CURING AGENT ECA 29 is a mixture of aliphatic polyamines derived from ethylenediamine and has an AHEW (amine-hydrogen equivalent weight) in the range of 36-38. Consisting of higher oligomers of TETA (triethylenetetramine), EPOXY CURING AGENT ECA 29 amine may be particularly useful as an epoxy curing agent in applications where higher Tg (glass transition temperature) and reasonably fast reactivity are needed with longer pot-life than DETA or TETA hardeners. As illustrated by the following figure, the increasingly fast gel times with standard bisphenol A based epoxies of the ethyleneamine series EDA (AHEW = 15.03), DETA (AHEW = 20.6), and TETA (AHEW = 24.4) are attributable to their increasing functionality and to them being aliphatic amines. For these three amines, the gel times shorten through the series, even though their AHEWs are increasing, which decreases the concentration of reactants in stoichiometric mixtures. As might be expected, the amines with higher AHEW, and therefore lower amine group concentrations in the formulations, have somewhat lower maximum exotherm temperatures. EPOXY CURING AGENT ECA 29 amine follows this trend of having a slightly lower exotherm temperature, however it provides a longer working time until gelation than do the lower functionality amines DETA or TETA. This is attributed to the higher proportion of secondary amino groups in this product. The high functionality of this amine also increases the level of crosslinking in the fully cured epoxy, resulting in a relatively high Tg of 143°C.

Functions: Curing Agent, Curing Agent, Curing Agent, Intermediate

Chemical Family: Epoxy & Epoxy Derivatives

End Uses: Composites, Industrial Castings, Sheets

Compatible Polymers & Resins: Epoxies (EP)

Processing Methods: Casting

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Enhanced TDS

Identification & Functionality

Features & Benefits

Applications & Uses

Compatible Polymers & Resins
Plastics & Elastomers End Uses
Plastics & Elastomers Processing Methods
Application Information
  • Epoxy Curing Agent ECA 29 can be of particular utility in applications where TETA (triethylenetetramine) cannot provide sufficiently long pot-life or sufficiently high Tg (glass transition temperature) when used to cure standard liquid epoxy resins. Another advantage of this product is that it produces considerably lower maximum exotherm temperatures than TETA when cured in thick sections, thus pointing to particularly utility when molding large castings or composites since it may allow molding in thicker sections or at higher component temperatures, thus allowing faster infusion of epoxy formulations into various types of reinforcements used to form composite materials.
  • The mechanical properties and glass transition temperatures of epoxy resins cured with Epoxy Curing Agent ECA 29 to form unfilled, cast sheets, are shown in the following table. The numbers given in parentheses are the coefficients of variation of the property values.
  • Properties of a standard liquid epoxy resin (EEW = 186) cured with 19.9 phr of Epoxy Curing Agent ECA 29 amine, baked 3 hours at 80°C + 2 hours at 135°C:
Tensile Strength, ultimate 9,860 psi (4.16)   68.0 MPa
Tensile Modulus

372,000 psi (1.22)

  2.56 GPa
% Elongation at Break 5.37 (10.2)   5.37
Flexural Strength

13,900 psi (0.46)

  95.8 MPa
Flexural Modulus

381,000 psi (0.67)

  2.63 GPa

 

Properties

Physical Form

Regulatory & Compliance

Technical Details & Test Data

Viscosity vs. Time for Various Amines and Standard DGEBA Resin

Epoxy Curing Agent ECA 29 - Viscosity vs. Time for Various Amines and Standard DGEBA Resin - 1

Safety & Health

Toxicity and Safety
  • Because of the fragility of eye tissue, almost any eye contact with any ethyleneamine may cause irreparable damage, even blindness. A single, short exposure to ethyleneamines, may cause severe skin burns, while a single, prolonged exposure may result in the material being absorbed through the skin in harmful amounts. Exposures have caused allergic skin reactions in some individuals. Single dose oral toxicity of ethyleneamines is low. The oral LD50 for rats is in the range of 1000 to 4500 mg/kg for the ethyleneamines.
  • The principal hazards that arise in working with Epoxy Curing Agent ECA 29 are those associated with similar organic amines; namely, a corrosive action on skin and eyes. Precautions should be taken to prevent contact with these parts of the body such as by use of protective clothing and chemical goggles. If contact occurs, immediately flush the exposed area with plenty of water for at least 15 minutes. Eye exposures should be examined by a physician. Contaminated clothing should be laundered before reuse. If ingestion occurs, do not induce vomiting. Have the individual drink a large amount of water (or milk, if it is readily available) and transport them to a medical facility immediately.

Packaging & Availability

Packaging Information

Epoxy Curing Agent ECA 29 is available in bulk and in 55-gallon drums of 205 Kg net weight.

Storage & Handling

Storage Informatin
  • Because of the fragility of eye tissue, almost any eye contact with any ethyleneamine may cause irreparable damage, even blindness. A single, short exposure to ethyleneamines, may cause severe skin burns, while a single, prolonged exposure may result in the material being absorbed through the skin in harmful amounts. Exposures have caused allergic skin reactions in some individuals. Single dose oral toxicity of ethyleneamines is low. The oral LD50 for rats is in the range of 1000 to 4500 mg/kg for the ethyleneamines.
  • The principal hazards that arise in working with Epoxy Curing Agent ECA 29 are those associated with similar organic amines; namely, a corrosive action on skin and eyes. Precautions should be taken to prevent contact with these parts of the body such as by use of protective clothing and chemical goggles. If contact occurs, immediately flush the exposed area with plenty of water for at least 15 minutes. Eye exposures should be examined by a physician. Contaminated clothing should be laundered before reuse. If ingestion occurs, do not induce vomiting. Have the individual drink a large amount of water (or milk, if it is readily available) and transport them to a medical facility immediately.

Other

Appearance
Amber to brown clear liquid
Chemical Properties
ValueUnitsTest Method / Conditions
Amine Value1200.0-1300.0 mg KOH/gmg KOH/gST-31.173
pH11.6-
Physical Properties
ValueUnitsTest Method / Conditions
Boiling Point250.0 °C°C
Density1.01 g/mLg/mL
Flash Pointmax. 182.0 °C°CPensky-Martens Closed Cup (PMCC)
Specific Gravity1.01-