PROBIMER® 77-7179 / Hardener 77-7180

PROBIMER® 77-7179 / 7180 is a photoimageable, negative-working solder mask optimized for flood screen print application. Probimer 77 7179/7180 Solder Mask exhibits a semi-matte surface and offers high process flexibility and excellent small hole developability with a high aspect ratio. It is developed in an aqueous alkaline solution.

RTU Product Type: 2K (2 component) Coating Resin System

Chemical Family: Epoxy & Epoxy Derivatives, Methacrylates

Features: Broad Processing Window, Good Adhesion, Good Electrical Properties, Good Flexibility, High Aspect Ratio, High Dielectric Strength, High Performance, High Resolution, Long Holding Time

Cure Method: Heat Cure, Radiation Cure

Enhanced TDS

Identification & Functionality

Features & Benefits

Ready-to-Use Product Features
Product Features
  • Two-component-system, semi-matte surface
  • High resolution
  • Excellent small hole developability with high aspect ratio
  • Optimized for long hold times between individual process steps
  • Wide process windows offer high flexibility
  • Excellent chemical, electrical and physical end properties
  • Fulfills the requirements of IPC SM-840, classes H&T
  • Corresponds to the requirements of well-known OEMs
  • High comparative index (CTI) and high dielectric strength
  • Excellent adhesion of conformal coatings
  • High resistance with aggressive post solder mask processes
  • Ideally suited for SIT process (Second Image Transfer)
Product Properties
  • High resolution
  • Excellent small hole developability with high aspect ratio
  • Wide drying window
  • Long hold times after drying and exposure
  • High comparative tracking index (CTI)
  • High dielectric strength
  • Excellent adhesion of legend inks and conformal coatings
  • High resistance with aggressive post solder mask processes
  • Well proven for applications in automotive and mobile PCB
Product Features
  • High resolution
  • Excellent small hole developability with high aspect ratio
  •  Wide drying window
  •  Long hold times after drying and exposure
  •  High comparative tracking index (CTI)
  •  High dielectric strength
  •  Excellent adhesion of legend inks and conformal coatings
  •  High resistance with aggressive post solder mask processes
  •  Well proven for applications in automotive and mobile PCB
Product Advantages
  • Two-component-system, semi-matte surface
  • High resolution
  •  Excellent small hole developability with high aspect ratio
  • Optimized for long hold times between individual process steps
  • Wide process windows offer high flexibility
  • Excellent chemical, electrical and physical end properties
  • Fulfills the requirements of IPC SM-840, classes H&T
  • Corresponds to the requirements of well-known OEMs
  • High comparative index (CTI) and high dielectric strength
  •  Excellent adhesion of conformal coatings
  • High resistance with aggressive post solder mask processes
  • Ideally suited for SIT process (Second Image Transfer)

Applications & Uses

Properties

Flame Rating
Physical Form

Regulatory & Compliance

Certifications & Compliance

Technical Details & Test Data

Exposure

Exposure: A hold time prior to exposure is not necessary. The spectral sensitivity is in the range of 350 - 420 nm. The exposure time depends on the parameters for the developing step.

Process Parameters Value Unit Test method
Energy 150 - 300 mJ/cm² ORC UV-351
Stouffer step on Cu clear 10 - 13  

21-step, ΔD = 0.15

Hold time after exposure not required    
Room Requirements on Working Environment

In order to reach best results the following room requirements should be respected:

  1. Room Temperature: 22 ±2 °C (71.6 ± 35.6 °F)
  2. Relative Humidity 50 ± 5%
  3. Cleanroom Class 100’000
  4. Overpressure Cleanroom + 3 mm WS
UV Cure

After thermal curing, we recommend UV curing of 1000–2000 mJ/cm2 for increased chemical resistance.

Exposure

A hold time prior to exposure is not necessary. The spectral sensitivity is in the range of 350 - 420 nm. The exposure time depends on the parameters for the developing step.

Process Parameters From To Standard
Energy (mJ/cm2), ORC UV-351 150 300 225
Stouffer step on Cu clear (21-step, D = 0.15) 10 13 12
Hold time after exposure Not required    
Inspection & Stripping

In case of mishandling during exposure, such as mis-registration, boards can be stripped at 60-80 °C (140-176 °F) with 10% NaOH solution.

Screen Printing
  • PROBIMER® 77 7179/7180 Solder Mask is applied to printed wiring boards using vertical or horizontal screen printing equipment. Monofilament polyester mesh in the range of 32-43 (mesh/cm) or 80-110 (mesh/inch) is recommended.

Final Curing

Thermal curing is required to ensure optimal properties in the cured film. It can be done in a standard convection oven.

Process Parameters From To Standard
Air temperature in °C(°F) 145 (293) 155 (311) 150 (302)
Temperature hold time (min) 45 70 60

After curing PROBIMER® lacquers exhibit extremely high chemical resistance and, thus, cannot be easily removed without damaging the board.

 

Flash-off/Drying

A flash-off time of 10 minutes or more before drying is recommended. To achieve good performance in resolution, developability of small holes and resistance to finishing processes, the coated boards must be dried according to the following parameters:

Process Parameters Side Time Temperature
Horizontal coating Side 1
Side 2
15-20 min.
35-45 min.
80-85 °C
(176-185 °F)
80-85 °C
(176-185 °F)
Vertical (Double-sided) Side 1 and 2 40-60 min. 80-85 °C
(176-185 °F)
Ink Mixing
  • Thoroughly mix these two components for 10-15 minutes. Mixing should be done with gentle mechanical stirring or shaking. High shear mixing must be avoided in order to prevent entrapment of large amounts of air, which can cause bubbles and poor leveling of printed coating.
  • Hold time of 30 min before use is recommended after ink mixing. In specific cases a diluent may be added. We recommend a maximum dilution of 3% with Dipropyleneglycolmonomethylether (DPM).
Developing

A hold time prior to exposure is not necessary. The spectral sensitivity is in the range of 350 - 420 nm. The exposure time depends on the parameters for the developing step.

Process Parameters From To Standard
Developing temperature in °C (°F) 30 (86) 35 (95) 32 (89.6)
Dwell time under spray (sec) 60 90 60
Spray pressure in MPa (PSI) 0.2 (30) 0.3 (40) 0.2 (30)
Pre-Cleaning
  • For a good adhesion of the lacquer we recommend chemical and/or mechanical pre-cleaning. Hold times prior to coating have to be minimized, since oxidation may impair the adhesion of the lacquer. Only completely dried boards should be coated, this has to be ensured especially for boards with small holes or blind vias.

Pot Life

Pot Life: At room temperature the ready-to-use mixture has a pot life of 3 days. (Definition of pot life is related to increased dwell time in developer.)

Pre-Cleaning Information

Pre-Cleaning: For a good adhesion of the lacquer we recommend chemical and/or mechanical pre-cleaning. Hold times prior to coating have to be minimized, since oxidation may impair the adhesion of the lacquer. Only completely dried boards should be coated, this has to be ensured especially for boards with small holes or blind vias.

Screen Printing Information

Screen Printing: PROBIMER® 77-7179 / 7180 is applied to printed wiring boards using vertical or horizontal screen printing equipment. Monofilament polyester mesh in the range of 32-43 (mesh/cm) or 80-110 (mesh/inch) is recommended.

Processing Information

UV Cure

  • After thermal curing, we recommend UV curing of 1000–2000 mJ/cm2 for increased chemical resistance.

Legend Inks and Conformal Coatings

  • In general, legend inks and conformal coatings exhibit good to excellent adhesion to boards coated with Probimer 77 7179/7180 Solder Mask. However, due to the large variety of available products preliminary trials are strongly recommended.

Production Release Trials

  • A variety of flow agents, soldering machines and soldering techniques as well as cleaning processes are used to mount components on circuit boards. Adjustment of the processing parameters and design guidelines to ensure optimal use of solder masks leads to the best overall results. Users should carry out their own tests prior to release for production runs.
Inspection and Stripping Information

Inspection and Stripping: In case of mishandling during exposure, such as mis-registration, boards can be stripped at 60-80 ℃ (140-176 ℉) with 10% NaOH solution.

Fiinal Curing Information

Thermal curing is required to ensure optimal properties in the cured film. It can be done in a standard convection oven.

Process Parameters Value Units
Air Temperature 145 - 155 °C
Temperature Hold Time 45 - 70 min

After curing Probimer lacquers exhibit extremely high chemical resistance and, thus, cannot be easily removed without damaging the board.

Room Requirements on Working Environment

Room Requirements on Working Environment: In order to reach best results the following room requirements should be respected:

  • Room Temperature: 20 - 24 ℃
  • Relative Humidity: 45 - 55%
  • Cleanroom Class: 100’000
  • Overpressure Cleanroom: + 3 mm WS
  • UV blocked light
Ink Mixing Information

Ink Mixing: Thoroughly mix these two components for 10-15 minutes. Mixing should be done with gentle mechanical stirring or shaking. High shear mixing must be avoided in order to prevent entrapment of large amounts of air, which can cause bubbles and poor leveling of printed coating. Hold time of 30 min before use is recommended after ink mixing. In specific cases a diluent may be added. We recommend a maximum dilution of 3% with Dipropyleneglycolmonomethylether (DPM).

Developing Information

Developing: The areas of unexposed PROBIMER® 77-7179 / 7180 should be developed in a continuous spray developing line. Developing is carried out in a 0.8-1.2% Na2CO3 aqueous alkaline solution.

Process Parameters Value Unit Conditions
Developing temperature 30 - 35 °C  
Dwell time 60 - 90 sec under spray
Spray pressure 0.2 - 0.3 MPa  
Flash-off / Drying Information

Flash-off / Drying: A flash-off time of 10 minutes or more before drying is recommended. To achieve good performance in resolution, developability of small holes and resistance to finishing processes, the coated boards must be dried according to the following parameters:

Process Parameters Side Time Temperature
Horizontal Coating Side 1 15-20 min

80-85°C (176-185°F)

Horizontal Coating Side 2 35-45 min

80-85°C (176-185°F)

Vertical (Double-sided) Side 1 and 2 40-60 min

80-85°C (176-185°F)

Storage & Handling

Storage Information
  • PROBIMER® lacquers are complex chemical compounds. To ensure that thesemproducts exhibit consistent quality in application we recommend storage under thefollowing conditions:
  1.  PROBIMER® 77/7179 Solder Mask in original container at 5-25 °C (41-77 °F)
  2.  Hardener 77/7180 Solder Mask in original containers at 5-25 °C (41-77 °F)
Storage Conditions

Probimer lacquers are complex chemical compounds. To ensure that these products exhibit consistent quality in application we recommend storage under the following conditions:

  • Probimer® 77/7179 Solder Mask in original container at 5-25 ℃ (41-77 ℉)
  • Hardener 77/7180 Solder Mask in original containers at 5-25 ℃ (41-77 ℉)

Under ‘EXP’ on the package label, the expiry date is indicated. Within this period the product should be used.

Pot Life
  • At room temperature the ready-to-use mixture has a pot life of 3 days. (Definition of pot life is related to increased dwell time in developer.)

Handling Information

PROBIMER® 77-7179 / 7180 contain flammable solvents. Contact with heat, spark and open flame is hazardous.

Other

Application Information
ValueUnitsTest Method / Conditions
Mix Ratio0.22 %(W)%(W)Hardener : Resin