PROBIMER® 88-92101 / HARDENER 88-99001

PROBIMER® 88-92101 / HARDENER 88-99001 is a photoimageable, negative-working solder mask optimized for flood screen print application. The solder mask exhibits a semi-matte surface and has high temperature resistance. Probimer 88 92101 is halogen-free and meets the requirements of the JPCA standard. It is developed in aqueous alkaline solution.

RTU Product Type: 2K (2 component) Coating Resin System

Application Area: Automotive Applications, Printed Circuit Boards

Chemical Family: Epoxy & Epoxy Derivatives, Methacrylates

Features: Broad Processing Window, Electrical Corrosion Resistant, Enhanced Physical Properties, Excellent Long Term Heat Aging Properties, Good Electrical Properties, High Aspect Ratio, High Flexibility, High Resolution, High Temperature Resistance, Leaching Resistant, Low Temperature Drying, Semi-Matt Finish, Thermal Cycling Resistant

Cure Method: Heat Cure

Enhanced TDS

Identification & Functionality

CAS Number
5026-74-4
Chemical Family
EC Number
225-716-2
Function
Binder
RTU Product Type
Technologies
Product Families

Features & Benefits

Labeling Claims
Ready-to-Use Product Features
Product Highlights
  • Green semi-matt version
  • High thermal cycling resistance
  • High thermal aging resistance
  • Halogen-free exceeds JPCA Standard
  • Low drying temperature level
  • No leaching in final finishing chemistries
  • High resistance with aggressive post solder mask processes
  • High resolution in bar code laser process
  • Excellent small hole developability with high aspect ratio
  • Excellent performance in e-corrosion resistance
Features and Benefits
  • Two-component-system, semi-matt surface
  • High resolution and definition
  • Wide process windows offer high flexibility
  • Excellent chemical, electrical and physical end properties
  • Fulfills the requirements of IPC SM-840-E, classes H & T
  • Corresponds to the requirements of well-known OEMs
  • High resistance with aggressive post solder mask metal finishes
Product Features
  • Two-component-system, semi-matt surface
  • High resolution and definition
  • Wide process windows offer high flexibility
  • Excellent chemical, electrical and physical end properties
  • Fulfills the requirements of IPC SM-840-E, classes H & T
  • Corresponds to the requirements of well-known OEMs

Applications & Uses

Regulatory & Compliance

Technical Details & Test Data

Flash-off/Drying Information

Flash-off/Drying: A flash-off time of 30 minutes before drying is recommended. To achieve good performance in resolution, developability of small holes and resistance to finishing processes the coated boards must be dried according to the following parameters

Process Parameters Side Time Temperature
Horizontal (single-sided) Side 1 15-20 min 70-80°C
Horizontal (single-sided) Side 2 20-30 min 70-80°C
Vertical (double-sided) Side 1 and 2 40-60 min 70-80°C

 

A maximum hold time of 24 hours between drying and development has to be complied.

 

Pot Life

Pot Life: At room temperature the ready-to-use mixture has a pot life of 1 day. (Definition of pot life is related to increased dwell time in developer.)

Ink Mixing

Ink Mixing: Thoroughly mix the resin component and the hardener component for 10-15 minutes. Mixing can be done by hand with a spatula or with gentle mechanical stirring. High shear mixing must be avoided in order to prevent entrapment of large amounts of air, which can cause bubbles and poor levelling of the printed coating. Hold the mixed content for at least 30 min for debubbling before use. In specific cases, to avoid coating bubbles between high copper tracks diluent may be added. The viscosity is preferably adjusted to 140~160 dpa.s in this case. We recommend a maximum dilution of 5% with Dipropyleneglycolmonomethylether (DPM).

Room Requirements on Working Environment

Processing Information: In order to reach best results the following room requirements should be respected:

  • Room Temperature: 20 - 24 ℃
  • Relative Humidity: 45 - 55%
  • Cleanroom Class: 100000
  • Overpressure Cleanroom: + 3 mm WS
  • UV blocked light
Screen Printing

Screen Printing: Probimer 88 / 92101 is applied to printed wiring boards using vertical or horizontal screen printing equipment. The recommended dry film thickness is 20-25µm. Monofilament polyester mesh in the range of 32-43 (mesh/cm) or 80-110 (mesh/inch) .

Developing Information

Developing: The areas of unexposed Probimer 88 / 92101 should be developed in a continuous spray developing line. Developing is carried out in a 1.0 % sodium carbonate aqueous alkaline solution

Process Parameters Value Units
Developing temperature 28 - 32 °C
Dwell time under spray 70 - 90 sec
Spray pressure 1.5 - 3 Bar
Final Curing Information

Thermal curing is required to ensure optimal properties in the cured film. It can be done in a standard convection oven.

Process Parameters Value Unit
Air Temperature 150 - 160 °C
Temperature Hold Time 60 - 90 min
Exposure

Exposure: A hold time prior to exposure is not necessary. The spectral sensitivity is in the range of 350 - 420 nm. The exposure time depends on the parameters for the developing step.

Process Parameters Value Unit test method Condition
Energy 300 - 500 mJ/cm² ORC UV-351  
Stouffer step on Cu clear 10 - 12    

21-step, ΔD = 0.15

 

Production Release Trials Information

Production Release Trials: A variety of flow agents, soldering machines and soldering techniques as well as cleaning processes are used to mount components on circuit boards. Adjustment of the processing parameters and design guidelines to ensure optimal use of solder masks leads to the best overall results. Users should carry out their own tests prior to release for production runs.

Pre-Cleaning

Pre-Cleaning: For a good adhesion of the lacquer we recommend chemical and/or mechanical pre-cleaning. Hold times prior to coating have to be minimized, since oxidation may impair the adhesion of the lacquer. Only completely dried boards should be coated, this has to be ensured especially for boards with small holes or blind vias.

Inspection and Stripping Information

Inspection and Stripping: In case of mishandling during exposure, such as mis-registration, boards can be stripped at 60-80°C (140-176 °F) with 10% NaOH solution. After thermal cure the boards could be stripped in 50% KOH at 60-80 °C (140-176 °F) for approx. 60 minutes.

Exposure

A hold time prior to exposure is not necessary. The spectral sensitivity is in the range of 350 - 420 nm. The exposure time depends on the parameters for the developing step.

Process Parameters from to standard
Energy (mJ/cm2), ORC UV-351 300 500 400
Stouffer step on Cu clear (21-step,D = 0.15) 10 12 11
Hold time after exposure not required

 

 

Final Curing

Thermal curing is required to ensure optimal properties in the cured film. It can be done in a standard convection oven.
 

Process Parameters from to standard
Air temperature in °C 150 160 155
Temperature hold time (min) 60 90 60
Developing

The areas of unexposed PROBIMER® 88 / 92101 should be developed in a continuous spray developing line. Developing is carried out in a 1.0 % Na2CO3 aqueous alkaline solution.
 

Process Parameters from to standard
Developing temperature in °C 28 32 30
Dwell time under spray (sec) 70 90 80
Spray pressure in Bar 1.5 3 2
Room Requirements on Working Environment

Room Requirements on Working Environment

Room Temperature 20 - 24 °C
Relative Humidity 45 - 55 %
Cleanroom Class 100’000  
Overpressure Cleanroom 3 mm WS
Flash-off/Drying

A flash-off time of 30 minutes before drying is recommended. To achieve good performance in resolution, developability of small holes and resistance to finishing processes the coated boards must be dried according to the following parameters:
 

Process Parameters side time temperature
Horizontal (single-sided) Side 1 15-20 min. 70-80°C
  Side 2 20-30 min. 70-80°C
Vertical (double-sided) Side 1 and 2 40-60 min. 70-80°C

A maximum hold time of 24 hours between drying and development has to be complied.

 

Pre-Cleaning

For a good adhesion of the lacquer we recommend chemical and/or mechanical pre-cleaning. Hold times prior to coating have to be minimized, since oxidation may impair the adhesion of the lacquer. Only completely dried boards should be coated, this has to be ensured especially for boards with small holes or blind vias.

Storage & Handling

Pot Life

At room temperature the ready-to-use mixture has a pot life of 1 day. (Definition of pot life is related to increased dwell time in developer.)

Storage Conditions

Probimer lacquers are complex chemical compounds. To ensure that these products exhibit consistent quality in application we recommend storage under the following conditions:

  • PROBIMER® 88-92101 in original container at 5-25 ℃ (41-77 ℉)
  • PROBIMER® 88-99001 in original containers at 5-25 ℃ (41-77 ℉)

Under ‘EXP’ on the package label, the expiry date is indicated. Within this period the product should be used.

Storage and Handling Information

PROBIMER® lacquers are complex chemical compounds. To ensure that these products exhibit consistent quality in application we recommend storage under the following conditions: PROBIMER® 88 / 92101 in original container at 5-25°C (41-77 °F) Hardener 88 / 99001 in original container at 5-25°C (41-77 °F) Under ‘EXP’ on the package label, the expiry date is indicated. Within this period the product should be used.

Other

Application Information
ValueUnitsTest Method / Conditions
Mix Ratio0.37 %(W)%(W)Hardener : Resin