ARALDITE® CY 225 / ARADUR® HY 227 / Filler Silica flour

• Very high mechanical and electrical properties
• Very high thermal shock resistance

Because both products contain accelerating additives, avoid storing them for extended periods at elevated temperatures. Correct handling of the components can result in undesirable viscosity increase, change in reactivity and substandard cured-state properties.

• Indoor electrical insulators for medium and high voltage, such as switch and apparatus components, bushings, instrument transformers and power transformers.
• Encapsulation of large metal components.

• Automatic pressure gelation process (APG)
• Conventional gravity casting process under vacuum

Fig.4.1: Viscosity increase at 40, 60 and 80°C (measurements with Rheomat 115)
(Shear rate D = 10 s-1)

Fig.4.2: Initial viscosity as a function of temperature
(measurements with Rheomat 115, D =10 s^-1)

Fig.4.1: Viscosity increase at 40 and 60°C (measurements with Rheomat 115)
(Shear rate D = 10 s-1)

Fig.4.2: Initial viscosity as a function of temperature
(measurements with Rheomat 115, D =10 s^-1)

The effective pot-life of the mix is about 2 days at temperatures below 25°C. Conventional batch mixers should be cleaned once a week or at the end of work. For longer interruptions of work, the pipes of the mixing and metering installations have to be cooled and cleaned with the resin component to prevent sedimentation and/or undesired viscosity increase. Interruptions over a week-end (approx. 48h) without cleaning are possible if the pipes are cooled at temperatures below 18°C.For data on viscosity increase and gel time at various temperatures, refer to Figs: 4.1 and 4.4.

Mould temperature
APG process : 130 - 160°C
Conventional vacuum casting : 70 - 100°C
Demoulding times (depending on mould temperature and casting volume)
APG process : 10 - 40 min
Conventional vacuum casting : 5 - 8h
Cure conditions : (minimal postcure)
APG process : 4h at 130°C or 3h at 140°C
Conventional vacuum casting : 12h at 130°C or 8h at 140°C

To determine whether crosslinking has been carried to completion and the final properties are optimal, it is necessary to carry out relevant measurements on the actual object or to measure the glass transition temperature. Different gelling and curecycles in the manufacturing process could lead to a different crosslinking and glass transition tempe- rature respectively.

Fig.4.4: Geltime as a function of temperature
(measured with Gelnorm Instrument, ISO 9396)

Fig.4.5: Glass transition temperature as a function od the cure time
(isothermic reaction, IEC 61006)

Thermal Endurance
Profile acc. IEC 60216

Thermal shock resistance

Fig.7.5: Crack resistance / Temperature shock test
Passed specimen (%) in function of the temperature steps
Mean failure temperature: - 88°C
Embedded metal parts with edge radius of 2 mm

System tested:
Araldite CY 205 IN / HY 905 IN / DY 040 / DY 061 / Silica.
Mix ratio: 100 / 100 / 10 / 1 / 410.
Determined on standard test specimen at 23°C.
Cured for 6h at 80°C + 10h at 130°C.

Fig.6.1: Loss factor (tan δ) and dielectric constant (εr) as a function of temperature measurement frequency: 50 Hz, IEC 60250/ DIN 53483)

Fig.6.2: Volume resistivity (ρ) versus function of temperature (measurement voltage: 1000 V, IEC 60093/ DIN 53482)

Araldite CY 205 IN / HY 905 IN / DY 040 / DY 061 / Silica.
Mix ratio: 100 / 100 / 10 / 1 / 410, cured for 6h at 80°C + 10h at 130°C.

Determined on standard test specimen at 23°C.

Fig.5.1: Shear modulus (G') and mechanical loss-factor (tan δ) as a function of temperature (measured at 1 Hz.)
(ISO 6721-7, method C)

Fig.5.2: Coefficient of linear thermal expansion (α) as a function of temperature (ISO 11359-2, reference temperature: 23°C)

Determined on standard test specimen at 23°C
Cured for 6h at 80°C + 10h at 130°C

Fig.6.1: Loss factor (tan δ) and dielectric constant (εr) as a function of temperature
(measurement frequency: 50 Hz, IEC 60250)

Fig.6.2: Volume resistivity (ρ) as a function of temperature
(measurement voltage: 1000 V, IEC 60093)

Determined on standard test specimen at 23°C
Cured for 6h at 80°C + 10h at 130°C

Fig.5.1: Shear modulus (G') and mechanical loss factor (tan δ) as a function of temperature (measured at 1 Hz.)
(ISO 6721, method C)

Fig.5.2: Coefficient of linear thermal expansion (α) as a function of temperature
(reference temperature: 23°C, ISO 11359-2)

System tested:
Araldite CY 205 / Aradur HY 905 / DY 040 / DY 061 / Silica
Mix ratio: 100 / 100 / 10 / 1 / 410

Thermal Endurance Profile IEC 60216

Fig.7.5: Glass transition temperature

Thermal Shock Resistance

Fig.7.5:Crack resistance / Temperature shock test
Passed specimen (%) as a function of the temperature steps
Mean failure temperature: - 49°C
Embedded metal parts with 2 mm radius

General instructions for preparing liquid resin systems

• Long pot life is desirable in the processing of any casting resin system. Mix all of the components together very thoroughly at room temperature or slightly above and under vacuum. Intensive wetting of the filler is extremely important. Proper mixing will result in:

1. better flow properties and reduced tendency to shrinkage
2. lower internal stresses and therefore improved mechanical properties on object
3. improved partial diskharge behavior in high voltage applications.

• For the mixing of medium- to high viscous casting resin systems and for mixing at lower temperatures, we recommend special degassing mixers that may produce additional selfheating of 10-15 K as a result of friction. For low viscous casting resin sys-tems, conventional mixers are usually sufficient.
• In larger plants, the individual components (resin, hardener) are mixed with the respective quantities of fillers and additives under vacuum. Metering pumps then feed these premixes to the final mixer or a continuous mixer. The individual premixes can be stored at elevated temperature (about 60°C) for up to about 1 week, de-pending on formulation. Intermittent agitation during storage is advisable to prevent filler sedimentation.
• Mixing time can vary from 0.5 to 3 hours, depending on mixing temperature, quantity, mixing equipment and the particular application. The required vacuum is 0.5 to 8 mbar. The vapor pressure of the individual components should be taken into account. In the case of dielectrically highly stressed parts, we recommend checking the quality consistency and predrying of the filler. Their moisture content should be <0.2%.

Specific Instructions

The effective pot-life of the mix is about 2 days at temperatures below 25°C. Conventional batch mixers should be cleaned once a week or at the end of work. For longer interruptions of work, the pipes of the mixing and metering installllations have to be cooled and cleaned with the resin component to prevent sedimentation and/or undesired viscosity increase. Interruptions over a week-end (approx. 48h) without cleaning are possible if the pipes are cooled at temperatures below 18°C. Viscosity increase and gel time at various temperatures.

Mold temperature
APG process: 130 - 160°C
Conventional vacuum casting: 70 - 100°C

Demolding times (depending on mold temperature and casting volume)
APG process: 10 - 40 min
Conventional vacuum casting: 5 - 8 h

Cure conditions
APG process (minimal postcure): 4h at 130°C or 3h at 140°C
Conventional vacuum casting: 12h at 130°C or 8h at 140°C

• To determine whether crosslinking has been carried to completion and the final properties are optimal, it is necessary to carry out relevant measurements on the actual object or to measure the glass transition temperature. Different geling and cure cycles in the manufacturing process could lead to a different crosslinking and glass transition temperature

respectively

Fig.4.4: Geltime measured with Gelnorm Instrument as a function of temperature
(ISO 9396)
A = 1 pbw DY 061 / B = 0.5 pbw DY 061.

Fig.4.5: Glass transition temperature as a function of the cure time
(isothermic reaction, ISO 11357-2)

Contamination of the eyes by resin, hardener or casting mix should be treatedimmediately by flushing with clean, running water for 10 to 15 minutes. A doctor should then be consulted.
Material smeared or splashed on the skinshould be dabbed off, and the contaminated area then washed and treated with a cleansing cream (see above). A doctor should be consulted in the event of severe irritation or burns. Contaminated clothing should be changed immediately.
Anyone taken ill after inhalingvapors should be moved out of doors immediately. In all cases of doubt call for medical assistance.

The components have to be stored in tightly sealed and dry original containers according to the storage conditions on the product label. Under these conditions, the shelf life will correspond to the expiry date stated on the label. Product specific advise regarding storage can be found on product label. After this date, the product may be processed only following reanalysis. Partly emptied containers should be closed tightly immediately after use.