ARATHANE® CY 11035-1 / ARATHANE® HY 11036

ARATHANE® CY 11035-1 / ARATHANE® HY 11036 is a liquid, 2-component polyurethane resin injection molding system, which can be applied as a foam by injection of an inert gas during molding. The system provides long pot life and is suited for large castings. It has a very low glass transition temperature and very good dielectric properties between – 60 °C and 120 °C. It is used in Gap filling in HV bushings, Filling of hollow core insulators, and Pressure-sensitive devices.

RTU Product Type: Casting Resin

Product End Uses: Bushings, Electronic Encapsulation, Electronic Sealing, Hollow Core Insulators, Insulators, Pressure Sensitive Devices

Chemical Family: Polyurethanes (PU)

Composites Processing Methods: Casting

Features: Excellent Dielectric Properties, Good Adhesion, Good Gap Filling Capabilities, Good Impregnation Capability, Good Mechanical Properties, Improved Storage Stability, Long Potlife, Low Exotherm, Low Glass Transition Temperature, Low Temperature Flexibility, Low Viscosity, Maintains Elasticity

  • TypeDocument Name
View All Documents

Enhanced TDS

Identification & Functionality

Features & Benefits

Labeling Claims
Ready-to-Use Product Features
Product Properties
  • Low viscosity and good impregnation capability
  • Solvent free and free of foaming agent
  • Long pot-life, low exotherm, suited for large bushings
  • Permanent elastic, mechanically strong, good adhesion
  • Temperature range -60 °C to 120 °C
  • Low dielectric losses
  • No filler, no sedimentation
  • Cures at 8 °C
  • Low water absorption

Applications & Uses

Properties

Physical Form

Technical Details & Test Data

Processing Information

Preparation of parts

  • The parts, which are to be casted, should be dry, clean and free of greases.

  • Preheating is not necessary, best temperature range for processing is between 18 and 40 °C, it also works at temperatures down to 8°C.

 

Mixing and Injection

  • Polyol and Isocyanate are mixed according to the specified mix ratio using preferably a two component metering and mixing machine.

  • High speed mixing head is preferred.
  • The foaming gas is injected during mixing at elevated pressure.
  • Molds to be filled preferably from the bottom side. Heights of several meters are possible.

 

Variation of mix ratio and effect on final properties

 

Mix ratio pbw 100/ 23 100/ 25 100/ 27
Shore A   30 42 47
Shore D   5 9 11
- - - Regular ratio -

 

Gel Time, Viscosity and Curing

 

Mix Viscosity at 25°C Rheomat mPa.s 2100 - 2600
Pot life at 25°C
(Time to reach 5000 mPa.s)
Rheomat min 40
(Time to reach 15000 mPa.s) Rheomat min 120
- Rheomat min 38
Geltime at 25 °C Gelnorm min 245
Geltime at 40 °C Gelnorm min 158
Geltime at 60 °C Gelnorm min 89
Geltime at 80 °C Gelnorm min 50

 

Cure Times

Minimum Curing Cycle:  72 hours at RT or Cure at max. 60°C possible 6 h 60°C

 

Mechanical and Physical Properties

 

System tested:
Arathane CY 11035-1 / HY 11036 = 100 / 25 pbw, in bulk, not foamed
Determined on unreinforced, cast standard test specimen at 23°C
Cured for 72 h at 23°C

 

Tensile strength ISO 527 MPa 2 - 3
Elongation at break ISO 527 % 150 - 250
E modulus from tensile test ISO 527 MPa 0.5 - 1
Flexural strength ISO 178 MPa 0.2 - 0.4
Elongation at break ISO 178 % 12 - 17
E modulus from flexural test ISO 178 MPa 1 - 2
Shear Modulus, DMA ISO 6721 MPa 6 - 7
Glass transition temperature (DSC) ISO 11357-2 °C - (60 - 70)
Coefficient of linear thermal expansion ISO 11359-2 ppm / K appr. 80
Mean value for temperature range: below -65°C
Thermal conductivity similar to ISO 8894-1 W/mK 0.19 - 0.2
Water absorption (specimen: 50x50x4 mm)
10 days at 23°C ISO 62 % by wt. 0.32 - 0.40
30 min at 100°C ISO 62 % by wt. 0.55 - 0.65
Density at 25°C ISO 1183 g/cm³ 1.15 - 1.20
FOAM density at 25 °C typical g/cm³ 0.35 - 0.40

 

Electrical Properties

System tested:


ARATHANE® CY 11035-1 / ARATHANE® HY 11036 = 100 / 25 pbw, in bulk, not foamed
Determined on unreinforced, cast standard test specimen at 23°C
Cured for 72 h at 23°C

 

 - 1

  • Breakdown strength IEC 60243-1 kV/mm 20 - 23
  • Tracking resistance IEC 60112 with test solution A CTI > 600 - < 1mm
  • Tracking resistance with test solution B CTI > 600M - < 1mm

 

 - 1

 

 - 1

Loss factor (tan delta) and dielectric constant (er) as a function of temperature
(measurement frequency: 50 Hz – 100 kHz)(IEC 250 / DIN 53483)

 

 - 1

Volume resistivity as a function of temperature (measurement voltage: 1000 V) (IEC 93 / DIN 53482)

 

FOAM tested:

Mechanical and Physical Properties

System tested:
ARATHANE® CY 11035-1 / ARATHANE® HY 11036 = 100 / 25 pbw as a foam
Flow rate on casting: ca. 120 ml/sec; 0.7 Liter /min
Blowing gas: Nitrogen
Spec. Weight of the specimen: 0.392 g/cm3; appr. 66% gas N2 in Foam
Closed cell foam, pore diameter < 1 mm


Note: Determined on foamed, cast standard test specimen at 23°C Cured for 72 h at 23°C

Flexural strength ISO 178 MPa 0.1 - 0.3
Elongation at break ISO 178 % 12 - 17
E modulus from flexural test ISO 178 MPa 1 - 2
Glass transition temperature (DSC) ISO 11357-2 °C - (65 - 70)
Density at 25°C in bulk: ISO 1183 g/cm³ 1.15 - 1.20
FOAM density at 25 °C - g/cm³ 0.35 - 0.40
Water absorption (specimen: 50x50x4 mm) ISO 62
10 days at 23°C - % by wt. 1.00 - 1.10

 

Heat conductivity as a function of density of foam, made with air or nitrogen

 

 - 1

Standard ISO 8894-2/07 (GLOW WIRE METHOD)
Specimen: 100X50X10 mm (directly casted into mould), made in Huntsman Labs

 

System tested:
ARATHANE® CY 11035-1 / ARATHANE® HY 11036 = 100 / 25 pbw, as a foam
Determined on foamed, cast standard test specimen at 23°C
Cured for 72 h at 23°C

Breakdown strength IEC 60243-1 kV/mm 10 - 14

 

 - 1

 

 - 1

Loss factor (tan delta) and dielectric constant (er) as a function of temperature (measurement frequency: 50 Hz – 100 kHz)(IEC 250 / DIN 53483)

 

 - 1

Volume resistivity (r) as a function of temperature (measurement voltage: 1000 V) (IEC 93 / DIN 53482)

 

Note:

  • CY 11035 /HY 11036 is the precursor of the actual system, based on ARATHANE® CY 11035-1 / ARATHANE® HY 11036
  • The technical difference is not significant.
  • One component of Polyol CY 11035 was no more available, a slight change to CY 11035-1 could not be avoided.

 

Processing methods: Casting with gas injection

Packaging & Availability

Packaging Information
  • ARATHANE® CY 11035-1 180KG Q4E
  • ARATHANE® HY 11036 25KG Q4E 

Storage & Handling

Storage Conditions
  • Store the components in a dry place according to the storage conditions stated on the label in tightly sealed original containers.
  • Under these conditions, the shelf life will correspond to the expiry date stated on the label.
  • After this date, the product may be processed only after reanalysis.
  • Partly emptied containers should be tightly closed immediately after use.
  • ARATHANE® HY 5610 must be protected from moisture. Storage tanks should be blanketed with dry air or nitrogen.
  • Storage at temperatures above 50°C is not recommended, since this can lead to the formation of insoluble solids and also the viscosity build-up increases on extended storage. Storage at low temperature is not recommended because it may lead to some crystallization.
  • Crystallized material must be melted out immediately by short time heating.
  • For information on waste disposal and hazardous products of decomposition in the event of a fire, refer to the Material Safety Data Sheets (MSDS) for these particular products.